Secondary treatment removes the soluble organic matter, nutrients such as nitrogen and phosphorus and most of the suspended solids that escape primary treatment.
Biological Secondary Treatment Processes
Most often, biological processes are used in which microbes metabolize organic compounds and nutrients to grow and reproduce. The two most common biological secondary treatment processes are attached growth and suspended growth systems. A suspended growth process fosters the growth of suspended microorganism flocs from individual organisms already present in the wastewater and in the return activated sludge.
The flocs contain organisms that can remove the pollutants through aerobic, anoxic and anaerobic environments. Once the pollutants are removed, the flocs are sent to a secondary clarification process where they separate from the water via gravity. A portion of sludge in the bottom of the secondary clarifier is then directed back upstream to blend with the primary effluent (Return Activated Sludge) to create mixed liquor. The remainder of the sludge is removed from the process (Waste Activated Sludge) to create the ideal ecology of microorganisms.
Attached growth systems rely on the microorganisms to attach to a media and create a biofilm. The settled sewage is either mixed or sprinkled over the biofilm coated media where the microorganisms remove the pollutants. Like the suspended growth process, biofilm fragments and suspended flocs are sent to a secondary clarifier for separation where sludge is recycled and wasted and clean water is discharged to the next process.
Organisms Require Nutrients in a Balanced Ratio
For biological treatment to function efficiently, organisms require nutrients in a balanced ratio, including carbon, nitrogen and phosphorus (referenced as C:N:P), as well as trace elements including iron, copper, zinc, nickel, manganese, potassium, sulfur and other components which are typically present in wastewater.
The commonly accepted C:N:P Ratio is 100:5:1, although some facilities thrive outside of this ratio, while others experience polysaccharide slime formation or filamentous bacteria growth that inhibit the biology and settling in the secondary clarifier.
Multiple biological processes can be employed to complete secondary treatment, including plug flow aeration basins, complete mix aeration tanks, sequencing batch reactors, oxidation ditches, trickling filters, moving bed biological reactors, integrated fixed film activated sludge and others.
Biological Nutrient Removal (BNR)
Biological Nutrient Removal (BNR) alters the environment of the microorganisms to remove nitrogen and phosphorus from the water. A BNR process consists of anaerobic (no oxygen or nitrate), anoxic (no oxygen, nitrate is present) and aerobic (oxygen present) stages, during which the water is moved through a series of chambers to perform various biological functions.
Chemical treatment processes can also be used, such as the chemical removal of phosphorus. By introducing a chemical precipitant within the aeration basin and clarifiers, phosphorus is removed by flocculation, binding into insoluble compounds that settle out and can be removed as sludge.
Process Step
Nitrogen Removal
- Is your process for Carbon and Nitrogen removal optimized?
- Do you control your Dissolved Oxygen levels manually, using a fixed set point or based solely on flow rates?
- Do you face significant electricity costs due to manual or fixed aeration controls?
Several technologies are used for Biological Nitrogen removal in wastewater treatment plants. From continuously-aerated treatment systems, to intermittent operated plants, sequencing batch reactors and more, nitrogen elimination is often the central process in the wastewater treatment plants. While variations exist, this process usually requires real-time measurement of ammonium and nitrate for adjustment of DO concentration and optimization of nitrification and denitrification times.
Phosphorus Removal
Is your Phosphorous removal process optimized?
Do you control the chemical dosing manually, using a fixed dosing amount or based solely on flow rates?
Do you face significant chemical costs due to manual or fixed dosing of chemicals?
Chemical phosphorus removal is a critical step in wastewater treatment. It is usually done by adjusting chemical dosing of precipitants, based on phosphate concentration and flow, allowing for consistent effluent phosphorus values. Hach offers solutions for your Phosphorous removal needs. Our solutions range from complete optimization and control of the Phosphorous removal process with Claros Process Management to instruments that cater to the specific parameters you need.
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