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Autosamplers show reliability, economy during survey studies
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“They were on the job, 24/7, and didn’t require overtime pay.” That’s Jarrod Shotts’ to-the-point assessment of Sigma 900 Series Portable Autosamplers. “And they’ll do the same for several future projects, including an upcoming distribution system profiling study,” he added.
Shotts, the Special Projects Coordinator for the Purification Department of the Birmingham, AL, Water Works Board, put Sigma portable autosamplers to work in a recent study examining sedimentation loading to raw water storage for the Shades Mountain Filter Plant. Three autosamplers, positioned around a basin at points receiving source water from the nearby Cahaba River, captured samples that were analyzed for total suspended solids (TSS). The TSS loading data gave engineers feasibility information for possible tank replacements in the existing receiving basin.
Samplers replace boats
Through the months of January and February, 2004, the tireless automated samplers consistently collected 200 mL samples every six hours, 24 hours a day. “They did the work of a small crew,” said Shotts. “Two of our sampler inlets were anchored under water at the point where pipes delivered the river water to the basin. Without the samplers, we would need two guys out in a boat, every six hours, to collect from these points, in who-knows-what weather. The samplers provided dependable, safe collection without the need for extra staff.
“Programming of the units was simple, then we just walked away and let them do what would have otherwise equated to expensive overtime labor.” He added that technicians simply harvested 12 sample bottles from each portable autosampler every other day, replacing them with empty bottles for the next sampling period.
Flexibility for other projects
Shotts explained the Birmingham Water Works Purification Department has been doing business with Hach for years. The 80-MGD Shades Mountain Filter Plant relies on 50 Hach process turbidimeters to monitor enhanced-coagulation filtration with dual-media filters. “Comparing sampler value with other products, and knowing Hach’s reputation, we chose the Sigma samplers,” he said.
“They offer flexibility for use in other projects. They accept a variety of sample containers, can collect composites, and are easily programmed for various routines.”
Shotts will use the Sigma Portable Samplers in an upcoming distribution system evaluation, collect-
ing samples for profiling of aluminum, coagulant, iron, and other key parameters 3900 miles of water system – again, saving significant labor costs. “In the saved labor, the autosamplers have probably already paid for themselves,” he said, “and we’re certainly not done with them yet.”
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Raw water for the Shades Mountain Filter Plant is pumped into a storage basin via vintage, 32-inch cast iron pipes. Operators anchored a sampler intake to one of these pipes with a C-clamp. Samplers then collected samples to monitor sedimentation loading. “We were very happy with this sampling solution,” affirmed Jarrod Shotts, above, Purification Department Special Projects Coordinator, checking another of the samplers.
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  Sigma 900 Series Portable Autosamplers stand watch at the Shades Mountain Filter Plant, at the intake pipe (above), and on the opposite shore (right). This Birmingham, AL, plant, one of the oldest in this part of the country, has used this basin for raw water storage since 1891 when it was built. Three autosamplers helped save significant labor costs in monitoring sedimentation input to the basin during a feasibility study targeting the design of new storage tanks. |
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Staff embraces LDO technology
for extended aeration control |
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Superintendent Dayne Yates at The City of Cornelia, GA, Water Pollution Control Plant is convinced the Hach LDO® Probe is the technology of choice at his plant, now and in the future. “The LDO unit is a great meter; I’m really pleased with it,” he emphasized.
Measuring dissolved oxygen (DO) is a significant task at this tertiary-treatment, plug-flow activated sludge plant located in northeast Georgia, about 90 miles northeast of Atlanta in Habersham County. The Biological Oxygen Demand (BOD) levels in plant influent range from 300 to 500 mg/L, depending on rainfall dilution. The DO at the aeration basin inlet typically ranges from 0.2 to 0.5 mg/L. An extended aeration process allows operators to adjust aeration for better ammonia removal, according to Yates.
LDO units replace ‘temperamental’ DO meters
Four different people – two treatment operators, the plant lab technician, and sometimes Yates himself – check DO about 9 am and 2 pm at aeration inlet and outlet daily to monitor oxygen available to, and consumed by, the processing microorganisms. DO values typically decrease in the afternoon, when attendants manually adjust blowers to maintain a DO concentration of 4.9 to 6.2 mg/L as the stream enters secondary settling.
The staff previously used three units of a membrane-type DO meter. “They’re temperamental. Just like people, they don’t respond similarly. Each of those meters performs differently.”
Time and ease-of-use benefits describe LDO
Yates enumerated the reasons he prefers the Portable Hach LDO Meter: no calibration or warm-up required, compared to the 30-40 minutes needed to prepare the membrane-type meter; the ease of use; quick response – no more than 1-2 minutes; and stable reading.
He also appreciates data logging for subsequent recall. “All our measurements are made on site, at the basins and occasionally during pretreatment monitoring, and this meter makes DO measurement one less thing to worry about doing.”
Lois Holden, the facility’s Laboratory Technician who has used the membrane-type dissolved oxygen meters since she started work there 12 years ago, agreed, “It takes so much less time than the old meter.”
Readings that can be trusted
Because the Hach LDO Meter responds quickly and is immune to the measurement error often associated with fouling of traditional sensors, it
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  Laboratory Technician Lois Holden uses the Portable Hach LDO® Meter at The City of Cornelia, GA, Water Pollution Control Plant. The 3.75-MGD facility has eight aeration cells that can be used in parallel or in series to adjust aeration for variable flow and load. |
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can be relied on for accurate readings. Yates explained how effluent from the facility’s contact chamber is sent down a tortuous spillway of multiple steps for thorough aeration prior to discharge. “Here, we are targeting saturation, and I would expect higher readings. When I see the Hach LDO Meter read slightly higher than the membrane-type meter at this discharge point – usually within 0.3 mg/L of the old meter – I believe the higher values provided by the LDO meter are correct.”
LDO is technique of the future
Expecting restrictions in permitted phosphorus concentrations, Yates is already discussing a facility upgrade that would include use of chemical precipitation and possibly anoxic treatment for augmented phosphorus removal. “If we go to the use of anoxic zones, we’ll want continuous DO monitoring to carefully control oxygen availability in each cell. I’ll definitely request an on-line LDO Probe,” he affirmed.
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 What's New?
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Next-generation spectrophotometer available soon
More than a laboratory instrument, it’s an analysis system!
The new DR/5000 UV-Vis Spectrophotometer automatically reads Hach barcoded TNT Plus™ reagent vials (see below), automatically recognizes the method needed, and automatically determines the reagent blank.
This instrument-reagent integration also yields 10-fold measurement and averaging – all to reduce reagent consumption and testing time while improving testing accuracy and productivity in any laboratory.
And, the DR/5000 Spectrophotometer incorporates a deuterium and tungsten halogen lamp for unparalleled optical stability and drift-free measurement typical of more expensive photometers. This flexible system uses a single cell adapter that holds the five most common sample vial types, a multiple-cell carousel adapter, pour-thru cell adapter, 13- and 16-mm cell compartment, and sipper module.
The DR 5000/Spectrophotometer includes the widest range of water analysis methods available in a single instrument, targeting water and wastewater treatment and process water control for nearly any industrial application. And a user-friendly touch screen puts you in complete control.
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 Barcoded vials speed tests, boost accuracy
New TNT Plus™ reagent vials are barcoded for automatic recognition and auto-blanking when used with  the DR/5000 Spectrophotometer – shaving time, error potential, and costs in your laboratory analyses.

And, TNT Plus reagent vials offer handling and performance improvements:

Superior optical glassware produces best precision

Flat-bottom vial improves handling

Leading off – Chemical Oxygen Demand (COD) TNT Plus reagent vials for low- and high-range tests using Hach USEPA-approved methodology:

TNT821 COD TNT Plus
(3-150 mg/L COD)
TNT822 COD TNT Plus
(20-1500 mg/L COD)

On deck – Look for TNT Plus reagent vials for nutrients and metals measurement, coming
this summer! |
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Sigma AV flow/level sensor targets collection systems
The new Sigma AV Sensor from Hach is the robust and flexible sensor designed particularly for the harsh environment of sewage collection systems. It comes with the option of two cover plates – a standard cover plate for most applications or an oil-filled cover plate that prevents fouling in extremely dirty installations.

The slim probe minimizes flow disturbance. Its sensor incorporates large, acoustic crystals and higher frequency for strong echo signals that yield exceptional velocity measurement accuracy and repeatability. Level measurement is optimized

with improved digital processing and temperature compensation in the pressure transducer. Operators enjoy single-point calibration – no bucket of water needed!
View details: Sigma AV Sensor
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Great news for you and the environment!
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Reliable COD reagent Hassle-free, affordable recycling Single-vendor convenience
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EZ COD Recycling: practical, affordable

A new, all-inclusive Hach EZ COD Recycling Service secures the lowest COD reagent recycling price possible for both small- and large-volume users of Hach COD reagent, and makes the recycling process easier than ever.
When you order your COD reagents from Hach, you can order EZ COD Recycling at the same time. You get a Department of Transportation (DOT)-approved, sealable recycling container and prepared documents. Just deposit the entire spent COD reagent vial in the container; when the container’s full, contact Heritage Environmental Services to schedule waste removal appropriate for your facility. It’s that easy! » view details
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Water surveillance tools from Hach Homeland Security Technologies (HST) target USEPA recommendations
These new tools model USEPA recommendations for field testing capabilities for initial water site characterization and water contamination assessment:

The Hach Eclox Water Test Kit features a chemiluminescence-method toxicity test, plus other vital screening tests. » view details

The Radalert™50 Nuclear Radiation Monitor provides on-the-spot checks of personal or area exposure, radiation leak and contamination detection, and identifies background radiation changes, anytime, anywhere. » view details

The Emergency Response Tool Kit combines the Radalert Monitor with Hach onsite tests for free chlorine, cyanide, pH, and conductivity. This efficient core field kit allows water attendants to react quickly, 24/7, to suspected or threatened water contamination. » view details

The Inspector Surface Contamination Monitor provides total or timed readings of radiation contamination on surfaces and in water. Use it separately or with the Emergency Response Tool Kit. » view details
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sc1000™ Controller networks sensors, expands communications
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Looking for economical price per measurement in process monitoring? Your solution is the new sc1000 Controller, which receives input from up to eight Hach digital sensors. With optional plug-in field bus cards, the sc1000 Controller communicates all sensor signals to an external network via MODBUS® or PROFIBUS DP protocol.
Like the sc100™ Controller that accepts up to two sensors, the new sc1000 Controller automatically recognizes Hach digital sensors for easy plug-and-play sensor installation in mix-and-match sensor configuration.
Building an sc1000 network by adding probe modules allows connection with up to 20 sensors and powerful communication and control options throughout a treatment plant. The portable sc1000 display module can be connected to any probe module for immediate graphics and data access via the color touch screen. Easy on training, installation, and capital budgets!
View details: Universal Controller/Mix-and-Match Digital Sensors
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Hach support programs
‘make it a lot easier for us’ |
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The Hach Field Service Partnership Program instituted at the Seminole County (Fla.) Water and Sewer Division of the Environmental Services Department is yielding operational and administrative benefits. Here’s another: the utility’s state inspector is satisfied, too.
Jack Cheney, Wastewater Operations Supervisor, reports the division adopted the service support plan in March 2004. “Our maintenance superintendent called it a ‘nobrainer.’ The Hach service manager visits our site and takes care of all scheduled maintenance and calibrations. He repairs analyzers that suffer power surges from lightning strikes – we have some spare analyzers on hand to cover us.
“A big benefit is that our DEP inspector is pleased to see instrument certification forms – completed, dated, and signed by the factory representative – on hand when he visits.
“And this plan suits our budgetary strategy of relying on contracting services when appropriate. The Service Partnership helps us contain O&M costs.”
Cheney indicated the division also relies on the Hach Scheduled Inventory Reagent Replacement (SIRR) Plan to receive fresh instrument reagents on a prearranged schedule. “The way I have it set up, we get the reagent about two weeks before we use it. And we get to take advantage of the quantity discount.
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| Seminole County Senior Operator David Engstrom checks pH readout in the instrumentation room of the chlorine contact chamber at the Greenwood Lakes WWTF. A Hach Field Service Partnership supports 58 on-line analyzers for chlorine, pH, nitrate, and turbidity and more than 30 spectrophotometers, colorimeters, turbidimeters, and pH/ion meters within the Seminole County Water and Sewer Division. |
“These plans make it a lot easier for us,” he summarized.
Hach also offers a Self Service Partnership Program in which Hach professionals train your staff on instrument troubleshooting and repair – even provide any parts that are needed. A third plan, the Bench Service Partnership Program, provides complete factory maintenance and repair, including parts, labor, and shipping.
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Coming to a state near you… HTTC regional workshops
Hach offers hands-on water analysis training classes at locations across the country. Get training on state-of-the-art equipment by experts in water analysis. Programs are designed for all levels of drinking water, wastewater, and industrial personnel.
We’ll help you ensure that you’re performing your water analysis correctly so that you achieve accurate results, every time. Many of our classes are state-approved for continuing education training credits. Hach HTTC can also provide customized training programs.
FREE regional Oxygen Demand Workshops and WebEx Seminars
Are you running BOD to meet NPDES permit requirements but would like to learn about using additional oxygen demand parameters for process control? How can you get the most benefit from the oxygen demand analyses you currently run? Do you test for COD but require convenient reagent disposal or a reagent that does not contain mercury?
Attend a FREE 2-hour workshop or join our FREE 1-hour on-line WebEx seminar and learn more about laboratory COD, TOC, and BOD. The workshop covers applications for oxygen demand testing in municipal wastewater and industrial processes. You’ll learn comprehensive details of each test including laboratory COD procedures, mercury-free COD methods, and simplified COD disposal. Topics also include TOC procedures and chemistries, BOD procedures, use of the BODTrak™ apparatus and how to establish a correlation between TOC or COD and BOD.

  1 hourWebEx sessions on May 5 at 9 am and 12 pm CST and May 6 at 9 am

  Springfield, IL, on May 10 from 10 to 12 with lunch provided

  Chicago, IL, on May 11 from 10 to 12 with lunch provided

  Houston, TX, May 18 from 10 to 12 with lunch provided

  Arlington, TX, on May 19 from 10 to 12 with lunch provided
WebEx on-line seminar information/registration: Technical Training area

Regional workshop information/registration: Course Descriptions (select state)

Or call HTTC at 1.800.227.4224, extension 6420.
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Hach Homeland Security
Technologies (HST) News |
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AWWA Water Security Congress attendees see Event Monitor at Oklahoma City plant

Utility managers, key security staff, public officials, and consultants participated in workshops and technical sessions at the AWWA 2005 Water Security Congress in April and saw the Event Monitor™ Trigger System in action in the City of Oklahoma City water distribution system.

Attendees heard in a technical session presented by the U.S. Army Engineer Research and Development Center how the Hach Event Monitor Trigger System has assisted in development of ‘fate & transport’ models of chemical and biological contaminants.

If you missed this congress, be sure to visit the Hach booth, #1213, at the AWWA annual conference in June
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| Drinking water professionals saw the Event Monitor™ Trigger System installed in tandem with the Hach Water Distribution Monitoring Trigger System and astroTOC UV On-line TOC Analyzer at a monitoring point of the Oklahoma City distribution system. |
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Event Monitor Trigger System receives ETV validation

A USEPA-sponsored Environmental Technology Verification (ETV) Program evaluation recently confirmed the performance of the Event Monitor Trigger System in detecting and ‘fingerprinting’ water quality changes related to water network-specific events. The system included the Hach Water
Distribution Monitoring Panel with sensors for turbidity, chlorine, pH, and conductivity, and the Hach astroTOC UV Online TOC Analyzer. Visit www.epa.gov/etv for complete ETV Program evaluation information.
 The Event Monitor system touch screen gives access to all system settings and sensor data, and lets operators ‘label’ system events.


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| Security monitoring evaluation with U.S. Army nears conclusion
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Hach HST is in the final stages of test and verification of its online monitoring systems in detecting criminal or terrorist prompted drinking water contamination.

Cooperative research being conducted with the U.S. Army Edgewood Chemical Biological Center and the Corps of Engineers Construction Engineering Research Laboratory is evaluating the Event Monitor Trigger System and off-the-shelf water quality sensors. The researchers are challenging a test water loop reflecting real-world water distribution systems with live threat agents to assess the instrumentation’s ability to detect and respond to the threats. The testing
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is taking place at Aberdeen Proving Ground, one of the few sites in country where such testing with actual chemical and biological agents can be conducted legally.

Utilities are currently applying these Hach water monitoring systems for characterization and management of water distribution systems. With verification from this cooperative study, water systems can be confident online monitoring with Hach systems provides a practical, real-time alert to adverse water attacks.

Watch for updates in the next issue of News & Notes newsletter and at www.hach.com!
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Chemiluminescence toxicity
test included in Eclox™ kit

Hach Homeland Security Technologies has combined the innovative Eclox™ toxicity method with proven Hach water quality tests to create the Hach Eclox Water Test Kit. This instrumental toxicity test was validated by the USEPA Environmental Technology Verification (ETV) program to reliably detect heavy metals, poisons, and chemical warfare agents on site.
The kit also includes Hach tests for pH, total dissolved solids (TDS), free and total chlorine, and color, along with reliable screening tests for pesticide/nerve agents and arsenic – a practical tool for first-response assessment of water supply contamination. Request literature 2404.
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The handheld Eclox luminometer makes toxicity evaluation fast and simple. Developed for the UK military, the technique has been validated by the USEPA ETV program – making it an ideal solution for municipalities looking for instrumental toxicity assessment and military specifications.
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Public works systems benefit from real-time remote monitoring for Chlorophyll and Cyanobacteria using Hydrolab DataSonde
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Many public water systems (PWSs), watershed management organizations, and government agencies that monitor and/or treat surface water from streams, rivers, lakes, and reservoirs commonly use traditional algae monitoring programs for identification and enumeration of algae. These fixed depth, periodic grab sample monitoring programs, while useful, often do not yield meaningful results in real-time. Only a few samples per day, at best, can be analyzed and labor and analysis costs are expensive.

Continuous monitoring solution
The Hydrolab DataSonde submersible water quality monitoring system, available from Hach, is equipped with integrated Chlorophyll a and Blue-Green Algae fluorometers from Turner Designs.

The DataSonde submersible systems are monitoring and surveillance platforms for vertical profiling as well as fixed depth continuous monitoring in the field. Detection is rapid and accurate using vivo fluorescence of algae-produced chlorophyll a and cyanobacteria (blue-green algae) phycocyanin pigments.

To start and optimize an effective surface water monitoring program, two Hydrolab DataSondes configured with two integrated fluorometers, one for chlorophyll a and a second for cyanobacteria
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phycocyanin, should be used. One would be used for vertical profiling and another for fixed depth continuous monitoring.

Detection of significant amounts of in vivo chlorophyll a and phycocyanin pigments with these could then be used to determine at what depths to take discrete field samples for algae identification and enumeration, taste and odor compound analysis, and cyanobacteria toxin testing.

Versatility too
The Hydrolab DataSonde can also be configured with many other relevant sensors including temperature, specific conductance, pH, dissolved oxygen, ORP, depth, salinity, and turbidity. Trend analysis of algal chlorophyll a and cyanobacteria phycocyanin pigments with these additional parameters creates a powerful water monitoring and treatment response tool. Even during periods when algae and cyanobacteria numbers are low and when algal blooms or taste and odor outbreaks have rarely occurred in the past, very useful data can be obtained to determine baseline conditions for predictive modeling during the more likely times.

For more information, please visit Hydrolab’s web site at www.hachenvironmental.com or call at 1.800.949.3766.
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Hach LDO® technology improves efficiency of pharmaceutical plant’s wastewater treatment process while saving costs
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Until relatively recently, the Bristol-Myers Squibb Company
(BMS) plant in East Syracuse, New York, sacrificed energy
efficiency to ensure its treatment system met or exceeded target
levels of dissolved oxygen (DO) in its aeration system.

Today, thanks to 24x7 monitoring using Hach LDO® (Luminescent
Dissolved Oxygen) technology, operators monitor the system
and respond to changes in the wastewater stream almost instantaneously.
Improved accuracy allows the system to operate much more
efficiently in an automatic mode of operation vs. the manual mode
previously used. A bonus is tremendous savings in energy costs.

The new technology monitors DO on-line in the aeration tanks
to provide operators with continuous, accurate DO readings. Used
with automated variable frequency drives (VFDs) that control aeration
blowers on a closed-control loop in direct response to DO measurements,
the system uses roughly 75% of the power it did before.
The result – substantial cost savings in both energy and maintenance,
letting BMS recoup the cost of the upgrade in less than a year.

Ideas for improvement
Operators had been trying to find a way to upgrade the aeration
process to improve its efficiency. The ideal solution the team envisioned
was to tie precise on-line DO monitoring to a blower control
system that would adjust aeration in response to DO measurements.
If DO readings indicated the process needed just a little more aeration,
a VFD could be used to provide just the right amount.

“Automating was something we always wanted to do,” notes
Dean Merritt, supervisor of the wastewater treatment plant, “but we
were limited by the operating temperature ranges of the DO monitors
on the market. The technology was just
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not available to allow us to do continuous monitoring.”

Breakthrough solution from Hach
When Hach introduced the Hach LDO monitor, with its breakthrough
technology for measuring dissolved oxygen, operators
were on the verge of substantially improving process efficiency.

“Certainly there was a cost factor, as we needed to purchase the
Hach meters and put VFDs on the blowers,” notes Merritt. “But the
savings and control we’ve realized as a result have been tremendous.
We set the system to maintain 2 ppm DO, and forget it. The
Hach LDO feeds the PLC a reading, and the PLC speeds up or
slows down the blowers to maintain 2 ppm DO. The DO measurements
are constant, repeatable and reliable, and the system is enormously
more effective and efficient than our old approach.”

The payoff
A Hach LDO probe on each tank helps BMS save $24,000/year
in energy costs. While the team hasn’t calculated other savings, they
speculate that they are substantial. For example, by eliminating
over-aeration, the load on the scrubbers that treat the air as part of
the odor control and abatement process has been reduced by 25%,
saving additional energy, labor, supplies, and maintenance costs.

“Before, if we got a DO level that was out of line, we would
turn a blower on,” notes Merritt. “What we didn’t know was
whether that condition had started just before the sample was taken,
or had it been at that level for some time? Because we didn’t want
to take any chances, we wasted air and energy. Now, we always
know what’s going on with the system, and we use the appropriate
amount of energy and air to keep it in control, automatically.”
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| See you at the Show!
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American Water Works Association Booth #1213
"The World's Water EventSM"
June 12 - 15, 2005, San Francisco, California

AESF SUR/FIN 2005 Booth #403
June 13 - 16, 2005, St. Louis, Missouri

Collection Systems
July 17 - 20, 2005, Boston, Massachusetts

International Food Expo Booth #705
July 17 - 20, 2005, New Orleans, Louisiana

Storm Con 2005 Booth #211/213
July 19 - 21, 2005, Orlando, Florida

International Bottled Water Association Booth #213
"Uncap the Future"
September 27 - 30, 2005, Orlando, Florida

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Hach will showcase many new products at AWWA
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The American Water Works Association (AWWA) Annual
Conference and Exposition, to be held this year in San Francisco,
promises to be the source for the information you need to meet
today’s challenges.

Join us at the Hach booth (#1213) to learn from our staff of
industry experts about cutting edge developments in technology
and applications. Ask questions, seek advice, and interact with us
regarding both universal water topics and products specifically
focused to meet your needs.

New Hach lab and on-line products

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The new DR 5000 UV-Vis Spectrophotometer works together
with a new array of TNT Plus reagent vials to improve testing
speed and accuracy. |

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The DR 2800 Spectrophotometer is the next generation of
portable instruments, also designed to work seamlessly with the
new TNT Plus reagent vials. |

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The UVAS sc UV Absorbance / % Transmittance Sensor
(right), together with a sc100 or sc1000 Controller, provides
continuous, automatic early warning of organic loading. |
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New Hach lab and on-line products
Much has changed in recent years as the world faces critical
issues, such as aging infrastructure, impacts of pending regulations,
and the continued importance of securing our water supply.

Hach Homeland Securities Technologies has a range of new
products to demonstrate at AWWA. Among them:

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The Eclox Kit which includes the innovative chemiluminescence
toxicity test. |

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A new Emergency Response Tool Kit which includes the
Radalert Monitor for testing radiation. |

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The WDM PipeSonde In-pipe Probe with
new chlorine test capability. |

Hach UVAS sc Sensor
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